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Q.

Which one of the following does not form addition product with $N a H S O_{3}$ solution

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a

$C_{6} H_{5} C O C H_{3}$

b

HCHO

c

$C H_{3} C H O$

d

$C_{6} H_{5} C H O$

answer is B.

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Detailed Solution

Aldehydes react with sodium bisulphite (sodium hydrogen sulphite) to give addition products. $C_{6} H_{5} C O C H_{3}$ does not give addition product with $N a H S O_{3}$ because of the presence of two bulky groups on the both sides of the carbonly carbon atom.

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