Q.

Which one of the following gives foul smell when heated with CHCl3 and caustic potash and also forms a diazonium salt as final product with Nitrous acid at 278K

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a

 

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b

 

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c

 

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d

 

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answer is D.

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Detailed Solution

:   (1), (2) , (4) –   1°amines

They all give foul smell with CHCl3+KOHalc on heating

But only (4) which is a 1°  aryl amine gives diazonium salt with NaNO2+HCl at 278K 

( 3 )….is a sec. amine ,it does not give positive carbyl amine test

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