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Q.

Which one of the following gives turbidity within a few minutes with HCl + anhydrous ZnCl2.

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a

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b

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c

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d

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answer is C.

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Detailed Solution

Lucas reagent is HCl+anhydrous ZnCl2;

10 alcohols do not give turbidity with Lucas reagent at room temperature;

20 alcohols give turbidity within few minutes with Lucas reagent;

30 alcohols give immediate turbidity with Lucas reagent;

Among the given options, alcohol derivative present in option (c) is secondary (or 20) and shows turbidity after few minutes of addition of Lucas reagent.

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