Q.

Which one of the following ions exhibits d-d-transition and paramagnetism as well?

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a

CrO42

b

Cr6O42

c

MnO42

d

MnO4

answer is C.

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Detailed Solution

In MnO4-2,  Mn is in the +6 oxidation state which means there is one d (d1) electron which gives rise to d-d transition and paramagnetism.

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Which one of the following ions exhibits d-d-transition and paramagnetism as well?