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Which one of the following ions is not tetrahedral in shape?

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${BF}_{4}^{-}$

${[Cu {({NH}_{3})}_{4}]}^{2 +}$

${[{NiCl}_{4}]}^{2 -}$

${NH}_{4}^{+}$

answer is C.

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Detailed Solution

${[Cu {({NH}_{3})}_{4}]}^{+ 2}$ is a special case.

But spectroscopic Studies showed:

Hybridization …… $s p^{2} d$
Geometry …….. Square Planar

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