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Q.

Which one of the following is correct for a spontaneous reaction at any temperature ?

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a

ΔH=-ve,ΔS=+ve,ΔG=-ve

b

ΔH=-ve,ΔS=-ve,ΔG=-ve

c

ΔH=+ve,ΔS=+ve,ΔG=-ve

d

ΔH=-ve,ΔS=+ve,ΔG=+ve

answer is B.

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Detailed Solution

A spontaneous reaction is a reaction that favors the formation of products at the conditions under which the reaction is occurring.

ΔH<0 and ΔS>0

ΔG=ΔH-TΔS

For the reaction to be spontaneous, ΔG should be negative, this works if ΔH is negative and ΔS is positive.

Hence the correct answer is (B) ΔH=-ve,ΔS=-ve,ΔG=-ve.

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