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Q.

Which one of the following is expected to exhibit optical isomerism ? (en = ethylenediamine)

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a

 Trans PtNH32Cl2

b

 Cis Co( en )2Cl2+

c

CisPtNH32Cl2

d

 Trans Co( en )2Cl2+

answer is C.

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Detailed Solution

Optical isomerism is not shown by square planar
complexes,   Cis PtNH32Cl2  and  Trans PtNH32Cl2 

Octahedral complex  Trans Co(en)2Cl2+ does not show optical isomerism (superimposable mirror image). ButCisCo(en)2Cl2+shows optical isomerism

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