Q.

Which one of the following is incorrect for ideal solution? 

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a

ΔP=Pobs -Pcalculated by Raoult's law =0

b

ΔHmix =0

c

ΔUmix=0

d

ΔGmix =0

answer is D.

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Detailed Solution

 For an ideal solution, ΔHmix=0,ΔVmix=0,

 Now, ΔUmix =ΔHmix -PΔVmix ΔUmix =0

 Also,for an ideal solution

pA=xApA°,pB=xBpB°

ΔP=Pobs -Pcalculated by =0

ΔGmix=ΔHmix-TΔSmix

 For an ideal solution, ΔSmix0

ΔGmix0

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