Q.

Which one of the following is not correct?

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a

For an ideal solution ΔmixH=0;ΔmixV=0

b

A mixture of phenol and aniline shows negative deviation in its vapour pressure.

c

A mixture of carbon disulphide and acetone shows positive deviation in its vapour pressure.

d

Nitric acid and water mixture shows large positive deviation in its vapour pressure and forms minimum boiling point azeotrope

answer is D.

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Detailed Solution

Option(d) is the answer

We know that the solutions which show large positive deviations in its vapour pressure form maximum boiling azeotropes.

But last statement Nitric acid and water mixture shows large positive deviation in its vapour pressure and forms minimum boiling point azeotrope states totally opposite.

Thus, it is incorrect.

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Which one of the following is not correct?