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Q.

Which one of the following is not isostructural with SiCl4?

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a

SO42-

b

PO43-

c

NH4+

d

SCl4

answer is C.

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Detailed Solution

  • SiCl4​ is tetrahedral as it has four chlorine atoms attached tetrahedrally where as SCl4​ has four chlorine atoms and a lone pair on sulfur which makes its structure see-saw and the remaining molecules are having tetrahedral geometry.
  • So SCl4​ is not isostructural with SiCl4​
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