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Q.

Which one of the following is the correct statement?

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a

B(OEt)3  imparts blue colour to the burner flame.

b

Boric acid is a protonic acid 

c

Hydrogen bonding in H3BO3 gives it a layered structure

d

Both Tl3+ and  Al3+ ions act as oxidsing agent in aqueous solution.

answer is C.

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Detailed Solution

Question Image

 

 

 

 

 

 

B(OEt)3  imparts green colour to the burner flame.k
A) It is a weak monobasic Lewis acid, soluble in water and in aqueous solution the boron atom completes its octet by accepting OH- from water molecules.
B(OH)3+2H2O[B(OH)4]+H3O+

B) Only Tl3+acts as an Oxidsing agent on account of inert pair effect. 

C)  In the solid state, the B(OH)3 units are hydrogen bonded together into two dimensional sheets with almost hexagonal symmetry.

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