Q.

Which one of the following is the weakest base?

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a

(C2H5)3N

b

(C2H5)2NH

c

C2H5NH2

d

NH3

answer is D.

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Detailed Solution

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In NH3 , there is no E.D.G. attached to N.

Basicity depends on the negative charge on the nitrogen atom or electron density. With an increase in the -ve charge on the nitrogen atom, the basicity of the amines increases. Basicity depends on charge density. Basicity decreases with a decrease in charge density.Resonance and inductive effects decrease the basicity of an amine.  Plus I effect will increase the basicity.
 

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Which one of the following is the weakest base?