Q.

Which one of the following mixture can act like a buffer?

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a

100 ml of 1 M HCl + 100 ml of 2M NaOH

b

100 ml of 1 M HCl + 50 ml of 4M NH4OH

c

50 ml of 2M HCl + 50 ml of 1M NH4OH

d

50 ml of 4 M HCl + 100 ml of 4M NaOH

answer is B.

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Detailed Solution

Mixture containing excess of weak base and limited strong acid acts like basic buffer.
(2) 
VaNa(SA)=100 milli equivalents VbNb(WB)=200 milli equivalents   S.A100 m.eq + W.B100 m.eq  Salt100 m.eq +H2O But excess W.B left = 100 m.eq ;
Solution contains 100 milli equivalents of NH4OH and 100 milli equivalents of NH4Cl. It is a basic buffer.

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