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Which one of the following octahedral complexes will not show geometrical isomerism (A and B are monodentate ligands)?

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$[{MA}_{5} B]$

$[{MA}_{2} B_{4}]$

$[{MA}_{3} B_{3}]$

$[{MA}_{4} B_{2}]$

answer is A.

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Detailed Solution

[MA₅B] is the octahedral complex that will not show geometrical isomerism.
These complexes does not have two same ligands that can either occupy adjacent positions or opposite positions.

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