Q.

Which one of the following on oxidation will not give a carboxylic acid with the same number of carbon atoms

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a

CCl3CH2CHO

b

CH3COCH3

c

CH3CH2CHO

d

CH3CH2CH2OH

answer is A.

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Detailed Solution

CH3- CO-CH3H2SO4K2Cr2O7 CH3COOH + HCOOH 

 One carbon atom is less in carboxylic acid than in the ketone group. 

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