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Q.

Which one of the following orders is not in accordance with the property stated against it?

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a

F2 > Cl2> Br2> I2 : Bond dissociation energy

b

F2> Cl2> Br2> I2 : Oxidising power

c

HI > HBr > HCl > HF : Acidic property in water

d

F > Cl > Br > I : Electronegativity

answer is A.

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Detailed Solution

X – X bond                 F – F     Cl – Cl      Br – Br       I – I
Bond dissociation       38         57              45.5         35.6
energy (kcal/mol)
The lower value of bond dissociation energy of fluorine is due to the high inter-electronic repulsions between non-bonding electrons in the 2p-orbitals of fluorine. As a result F - F bond is weaker in comparison to Cl – Cl and Br – Br bonds.

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