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Q.

Which one of the following reactions involves disproportionation?

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a

$2 H_{2} {SO}_{4} + Cu \to {CuSO}_{4} + 2 H_{2} O + {SO}_{2}$

b

${As}_{2} O_{3} + 3 H_{2} S \to {As}_{2} S_{3} + 3 H_{2} O$

c

$2 KOH + {Cl}_{2} \to KCl + KOCl + H_{2} O$

d

${Ca}_{3} P_{2} + 6 H_{2} O \to 3 Ca (OH)_{2} + 2 {PH}_{3}$

answer is C.

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Detailed Solution

A reaction, in which a substance undergoes simultaneous oxidation and reduction, is called disproportionation reaction. In these reactions, the same substance simultaneously acts as an oxidising agent and as a reducing agent. Here Cl undergoes simultaneous oxidation and reduction. $2 KOH + {Cl}_{2} \to KCl + KOCl + H_{2} O$

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Which one of the following reactions involves disproportionation?