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Q.

Which one of the following sets of conditions would result in a reaction that is spontaneous at high temperatures but non-spontaneous at low temperatures?

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a

ΔH>0,ΔS>0

b

ΔH>0,ΔS<0

c

ΔH<0,ΔS>0

d

ΔH<0,ΔS<0

answer is A.

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Detailed Solution

The sets of conditions would result in a reaction that is spontaneous at high temperatures but non-spontaneous at low temperature ΔH>0,ΔS>0.

ΔH and ΔS are negative; the reaction is spontaneous at low temperatures. And so, saying a process is spontaneous at “high” or “low” temperatures means the temperature is above or below, respectively, that temperature at which ΔG for the process is zero.

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