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Q.

Which one of the following statement is correct regarding maximum boiling azeotrope ?

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a

It shows positive deviations from Raoult's law

b

Total vapour pressure of the liquid mixture is lesser than expected from Raoult's law

c

Hmixing=+ve

d

Vmixing=+ve

answer is B.

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Detailed Solution

Azeotropic mixture is a constant boiling mixture.

At certain concentration, both liquids boil at same temperature.

It is not possible to separate them by fractional distillation.

Maximum boiling Azeotrope means higher boiling point than any of the two cmponents;

Lesser vapour pressure than expected from Raoult's law ;

A-B interactions are stronger than A-A and B-B interactions ;

Attractions dominate;

It shows negative deviations from Raoult's law

Hmix=-ve ; Vmix=-ve ; Gmix=-ve ; Smix=+ve ;

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