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Q.

Which one of the following statements is correct?

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a

Cyclohexadiene is an aromatic compound

b

Deactivating groups are ortho and para directing groups

c

Reaction of benzene with 1- chloropropane and anhydrous AlCl3 gives n-propyl benzene

d

Electrophilic substitution of benzene takes place via σ complex

answer is D.

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Detailed Solution

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Cyclohexadiene contains sp3carbon. Hence, it is not aromatic. For it to be an aromatic compound, all the carbon atoms must be sp2hybridized.

Deactivating groups are meta directing groups.

Benzene reacts with n-propyl chloride in presence of anhydrous AlCl3 leads to rearrangment, forming Isopropyl benzene.

Electrophilic substitution of benzene takes place via σ− complex or a stable arenium ion.

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