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Q.

Which one of the following statements is false?

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a

Two sucrose solutions of same molality prepared in different solvents will have the same freezing point depression.

b

The osmotic pressure (π) of a solution containing non-volatile solute is given by the equation, π=MRT where M is the molarity of the solution

c

Raoult’s law states that the vapor pressure of a component over a solution is proportional to its mole fraction in the solution.

d

The correct order of osmotic pressure for 0.01M aqueous solution of each compound is BaCl2>KCl>CH3COOH> sucrose 

answer is A.

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Detailed Solution

different solvents are having different molal depression in constant value(Kf), thus Tf of same molal solution containing same non-volatile solute in different solvent is diffferent

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