Q.

Which one of the following statements is false?

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a

Raoult's law states that the vapour pressure of a component over a solution is proportional to its mole fraction.

b

The osmotic pressure (Π) of a solution is given by the equation Π=MRT where M is the molarity of the solution.

c

The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is BaCl2>KCl>CH3COOH>sucrose.

d

Two sucrose solutions of same molality prepared in different solvents will have the same freezing point depression.

answer is D.

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Detailed Solution

The freezing point depression is given by ΔTf=Kfm. Different solvents have different values of Kf and hence show different freezing point depression.

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