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Q.

Which one of the following statements is false?

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a

Two sucrose solutions of same molality prepared in different solvents will have the same freezing point depression

b

The osmotic pressure (π) of a solution containing a non volatile solute is given by the equation π=MRT  , where M is the molarity of the solution

c

Raoult’s law states that the vapor pressure of a component over a solution is proportional to its mole fraction in the solution

d

The correct order of osmotic pressure for 0.01M aqueous solution of each compound is BaCl2>KCl>CH3COOH> sucrose

answer is A.

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Detailed Solution

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Different solvents will have different freezing points, hence same solute when dissolved in different solvents does not have same Tf

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