Q.

Which one of the following statements is false?

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a

The correct order of osmotic pressure for 0.01m aqueous solutions of each compound is BaCl2>KCl>CH3COOH>sucrose

b

The osmotic pressure (π) of a solution is given by the equation π=MRT, where M is the molarity of the solution 

c

Raoult’s laws states that the vapour pressure of a component over a solution is proportional to its mole fraction.

d

Two sucrose solutions of same molality prepared in different solvents will have same freezing point depression.

answer is D.

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Detailed Solution

ΔTf=iKfm Kf for different values for different solvents even if in ‘m’ is same ΔTf will be different.

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Which one of the following statements is false?