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Q.

Which one of the following statements is not correct? 

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a

Carbon-oxygen bond length in methanol  (CH3OH) is shorter than that of C-O bond length in phenol.

b

Acid strength of alcohols decreases in the following  RCH2OH>R2CHOH>R3COH

c

Alcohols are weaker acids than water (except CH3OH  )

d

The bond angle  Question Image in methanol is 108.90

answer is C.

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Detailed Solution

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The C – O bond lenth in alcohols is 142 pm and in Phenol it is 136 pm. The C – O bond length in phenol is shorter than that in methanol due to the conjugation of unshraed pair of electrons on oxygen with the ring, which imparts double bond character to the C – O bond.

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Which one of the following statements is not correct?