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Q.

Which one of the following statements related to lanthanons is incorrect?

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a

 Europium shows +2 oxidation state. 

b

The basicity decreases as the ionic radius decreases from Pr to Lu.

c

All the lanthanons are much more reactive than aluminium.

d

Ce(+4) solutions are widely used as oxidizing agent in volumetric analysis.

answer is C.

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Detailed Solution

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The reactivity of lanthanons are less than aluminium due to high I.P which arises due to lanthanoid contraction.
(1) Eu (II) has stable electronic confi-guration, i.e., [Xe] 4f7 5do 6so.
(2) As the size of the lanthanoid ions decreases, the covalent character of the hydroxides increases. Hence, basic strength decreases.
(4) Ce+4 is a good oxidizing agent and easily converted into Ce+3.

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