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Q.

Which one of the following will increase the voltage of the cell? 

Sn(s)+2Ag+(aq)Sn2+(aq)+2Ag(s)

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a

increase in the concentration of Ag+

b

none of the above 

c

increase in size of silver rod

d

increase in concentration of Sn2+

answer is C.

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Detailed Solution

Ecell=Ecello - 2.303RTnFlog[Sn2+][Ag+]2.

 Increase in the concentration of Ag+ decreases the value of  log[Sn2+][Ag+]2.

This results in the increased value of Ecell

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