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Q.

Which one of the Nitrogen atoms in
is the most nucleophilic?

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a

III

b

I

c

II

d

All three Nitrogen atoms are equally strong

answer is B.

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Detailed Solution

Nucleophiles are electron rich species and they attack on electron deficient centres.
In the given compound, nitrogen number II and III are in conjugation with the double bond of the carbonyl group.

And, nitrogen number I is free to donate its lone pair of electrons.

Thus, nitrogen I is the most nucleophile.

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