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Q.

Which set of quantum numbers is not allowed?

n,                 l,           ml,              ms

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a

1,    0,    0,    +12

b

2,    2,    1,    12

c

3,    1,    1,    12

d

4, 3, 3, +12

answer is B.

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Detailed Solution

The set of quantum numbers is not allowed is 2,    2,    1,    12

There can be no zero for the main quantum number (n). Therefore, the permitted values for n are 1, 2, 3, 4, and so forth. Any integer between 0 and n – 1 can serve as the angular quantum number (l). For instance, if n = 3, l might be one of 0, 1, or 2.

Hence, the option B is correct.

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