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Q.

Which solution has the greatest percent ionization?

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a

0.25 M HNO2Ka=4.5×104

b

1.00M HCOOHKa=1.7×104

c

2.00M CH3NH2Kb=4.4×104

d

0.10 M NH3Kb=1.8×105

answer is A.

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Detailed Solution

Ionization constant α to find :

α=kac; Highest is for b.

Kb=1.8×105C=0.1M

α2=Kbc=1.8×1050.1=1.8×104

α=0.0134

∴    Percentage ionization =1.34% which is highest of the four values given.

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Which solution has the greatest percent ionization?