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Q.

Which statement is correct about the initial precipitate that forms when a 0.10 M NaF solution is added slowly to a solution that is 0.10 M with respect to both Ca(NO3)2 and Mg(NO3)2?

Kap
CaF24×10-11
MgF26.4×10-9

 

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a

The initial precipitate will contain CaF2 only.

b

The initial precipitate will contain MgF2 only.

c

The initial precipitate will contain both CaF2 and MgF2 with more CaF2 .

d

 The initial precipitate will contain both CaF2 and MgF2 with more MgF2 .

answer is A.

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Detailed Solution

F-  required for pptn of CaF22×10-5

MgF22.5×10-4

Hence, CaF2 precipitates first.

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