Q.

Which statement(s) about coordination of cation is/ are true?

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a

Most metal ions exhibit only a single characteristic coordination number

b

For most cations, the coordination number depends on the size, structure and charge of the ligands.

c

The coordination number is determined solely by the tendency to surround the.metal atom with the same number of electrons as one of the rare gases.

d

The coordination number is equal to the number of ligands bonded to the metal atom

answer is D.

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Detailed Solution

A few metal ions display multiple coordination numbers. As a result, statement A is untrue.
The number of ligands in a coordination compound that are directly bound to the main metal atom or ion is known as the coordination number. Here, a sigma bond holds the monodentate ligand to the metal. As a result, statement B is untrue.
The propensity to surround the metal atom with the same amount of electrons as one of the rare gases determines the coordination number. There are also a number of other elements. As a result, choice C is incorrect.
The charge on a metal ion, the charge on the ligand, the relative sizes of the metal ion and the ligands, and other factors affect the coordination number of a metal ion

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