Q.

Which transition in the hydrogen spectrum would have the same wavelength as the Balmer transition n = 4 to n = 2 of He+ spectrum ?

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a

n = 2 to n = 1

b

n = 4 to n = 3

c

n = 5 to n = 3

d

n = 3 to n = 1

answer is A.

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Detailed Solution

1λ=RHZ2(1n121n22)

RHZH21n121n22=RHZHe+2122142 11n121n22=414116 1n121n22=34

n1=1, hence n2=2,3,4,..

For first line, n1=1 and n2=2

(1n121n22=11-14=34

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