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Q.

Which transition in the hydrogen spectrum have the same wavelength as Balmer transition, n = 4 to n = 2, of He+  spectrum?

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a

n1=1,  n2=2

b

n1=1,  n2=3

c

n1=3,  n2=4

d

n1=2,  n2=4

answer is A.

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Detailed Solution

ForHe+ion,1λ=Z2R1n121n22=22R122142=3R4For  hydrogen  atom,  1λ=R1n121n22So,    3R4=R1n121n22or       1n121n22=34i.e.,         n1=1  and  n2=2

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