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Q.

Which will have enantiomers?

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a

n - butyl chloride

b

ter - butyl chloride

c

sec - butyl chloride

d

iso - butyl chloride

answer is C.

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Detailed Solution

Compounds with a chiral carbon that can exhibit optical isomerism and can have non-superimposable mirror images are called enantiomers.
For (A) ${CH}_{3} - {CH}_{2} - {CH}_{2} - {CH}_{2} Cl$ has no chiral carbon, therefore cannot be an enantiomer.
For (B) $C {({CH}_{3})}_{3} Cl$ has no chiral carbon, therefore cannot be an enantiomer.
For (C) ${CH}_{3} - CHCl - {CH}_{2} - {CH}_{3}$ has a chiral carbon and can be an enantiomer.
For (D) $CH {({CH}_{3})}_{2} - {CH}_{2} Cl$ has no chiral carbon and cannot be an enantiomer.

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