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Q.

Which type of isomerism is shown by  Cr (en)2 ( NCS )2 SO4 and Cr (en)2 ( NCS )(SO)4NCS ?

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a

As hydrate isomers                                                      


 

b

As linkage isomers

 

c

 As ionization isomers                                                 

d

As coordination isomers

answer is C.

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Detailed Solution

Cren2NCS2SO4 gives Cren2NCS2+2 and SO42- on ionization, whereas Cren2NCSSO4NCS gives Cren2NCSSO4+ and NCS- on ionization. Hence, they are ionization isomers with same molecular formula.

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Which type of isomerism is shown by  Cr (en)2 ( NCS )2 SO4 and Cr (en)2 ( NCS )(SO)4NCS ?