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Q.

Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?

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a

ΔrGof Cu2S is greater than those of CS2 and H2S

b

Cu2S cannot be reduced by carbon or hydrogen

c

ΔfG of copper oxide is less than that of CO2

d

All of the above

answer is D.

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Detailed Solution

The standard free energy of formation (ΔfG) of Cu2S is greater than those of CS2 and H2S. So, Cu2S (pyrites) cannot be reduced by carbon or hydrogen.
2Cu2S+C4Cu+CS2 (Not feasible
  Cu2S+H22Cu+H2S (Not feasible
However, the ΔfG of copper oxide is less than that of CO2. Therefore, the sulphide ore is first converted to oxide by roasting and then reduced.
2Cu2S+3O2Roasting 2Cu2O+2SO2
2Cu2O+CHeat 4Cu+CO2[ Feasible ]

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