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Q.

Why primary amines have higher boiling point than tertiary amines ?

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a

Due to H bonding

b

due to less bulky mass

c

due to more availability of space

d

due to weak bonds

answer is A.

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Detailed Solution

Primary amines are more together and has more boiling points due to h bonding between the compounds .two hydrogens are present that forms hydrogen bonds compared to tertiary amine .

The intermolecular bonding increase. and hence the boiling point will be more due to need of more energy .

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Why primary amines have higher boiling point than tertiary amines ?