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Q.

With excess of water,  PCl5 gives, While the reaction of pentachloride with water gives phosphorus pentoxide and if excess water is provided the product formed is orthophosphoric acid.

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a

H4P2O7 + HCl

b

 H3 PO3 + HCI 

c

H3 PO2 + HCI 

d

H3 PO4 + HCI 

answer is A.

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Detailed Solution

PCl5+4H2O→5HC1+H3PO4

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