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Q.

With excess of water, ${PCl}_{5}$ gives, While the reaction of pentachloride with water gives phosphorus pentoxide and if excess water is provided the product formed is orthophosphoric acid.

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a

$H_{4} P_{2} O_{7} + HCl$

b

$H_{3} {PO}_{3} + HCI$

c

$H_{3} {PO}_{2} + HCI$

d

$H_{3} {PO}_{4} + HCI$

answer is A.

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Detailed Solution

${PCl}_{5} + 4 H_{2} O \to 5 HC 1 + H_{3} {PO}_{4}$

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