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Q.

With respect to halogen, four statement are given below:

(P) The bond dissociation energies for halogens art in the order: I2<F2<Br2<Cl2

(Q) The only oxidation state is -1.

(R) The amount of energy required for the excitation of electrons to the first excited state decreases progressively as we move from F to I.

(S)  They form HX2- species in their aqueous solution (X= halogen)

The correct statement are :

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a

P, Q and S

b

P, R and S

c

Q, R and S

d

P

answer is D.

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Detailed Solution

The bond dissociation energy of halogens is given in order: I2<F2<Br2<Cl2.

The bond dissociation energy decreases down the group, but fluorine shows remarkably small dissociation energy.

In halogens, there are two bonding pair and 3 nonbonding pairs. Because of the small size of fluorine, these non-bonding pairs come closer to each other and repel each other to a maximum extent which causes a decrease in bond strength.

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