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Q.

With respect to hypochlorite, chlorate and perchlorate ions, choose the correct Statements (s) 
 

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a

The hypochlorite ion is the strongest conjugate base. 

b

The molecular shape of only chlorate ion is influenced by the lone pair of electrons of Cl
 

c

The hypochlorite and chlorate ions disproportionate to give rise to identical set of ions. 
 

d

The hypochlorite ion oxidizes the sulphite ion 

answer is A, B, D.

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Detailed Solution

The structure of HClO and  HClO4 are as follows.

Question Image
The central atom in both HClO and  HClO4issp3
Reaction of  Cl2 with  H2O gives  HOCl Which decomposed to give reagent oxygen.
 Cl2+H2O[HCl+HOCl]2HCl+[O]
The conjugate base of HClO4 Is a weaker base than  H2O
HClO4 Is more acidic than HClO  Because of resonance stabilization of its anion.   
 

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