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Q.

With the decrease in lattice constant of a semiconductor ( if Ec, Eg, Ev represent the width of conduction band, energy gap and width of valency band) 

 

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a

All  Ec, Eg, Ev decrease 
 

b

Ec, Ev increase, but Eg decrease 

 

c

Ec, Ev decrease, but Eg increase 

 

d

All  Ec, Eg, Ev increase

answer is C.

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Detailed Solution

  • The cube's side length serves as the lattice constant. The space between the molecules or atoms that make up the lattice is represented by the word "lattice." 
  • Accordingly, a drop in lattice constant often means that electrons are more closely bound to the atom and so take more energy to escape, increasing the band gap.
  • On the other hand, valence (filled) and conduction (unfilled) bandwidth will both become smaller as a result of the contracting lattice parameter.

Hence the correct answer is Ec, Evdecrease, but Eg increase 

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