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Q.

With the help of the following equations and data choose the wrong statement.
ICH3HCH3+H
Eact=+435.1kJ
IICH3CH2HCH3C˙H2+HEact=+410.0kJ
IIICH3CH32CH3Eact=+368.0kJ
IV. CH3CH2CH2CH32CH3CH2 Eact=+368.0kJ
VCH3CH2CH2CH3CH3CH2CH2+CH3Eact=355.6kJ

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a

During homolysis of ethane at high temperature, the (C-C) bond breaks more radily than (C-H) bonds.

b

Formation of CH3CH˙2, radical by reaction (II) will take
place at lower temperature than the formation of C2H5 radical by reaction (IV).

c

Thermal cracking of (C-H) bond of methane occurs at 1500 K and that of (C-H) bond of ethane breaks at 800-900 K.

d

During the cracking of n-butane, reaction (IV) occurs more readily than reaction (V).

answer is D.

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Detailed Solution

Lower the Eact. of first step of chain propagation reaction, more easily the bond can be broken. Also this bond breaking will take place comparatively at a lower temperature.

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