With which one of the following elements silicon should be doped so as to give p-type semiconductor?

When a lower valent impurity is added to a  higher valent semi conductor it  is called P -type doping.

A 14^th group element having valency of 4 should be doped with 13^th group element with valency 3 to give p-type semiconductor.

Silicon should be doped with Group 13 element -Boron to give a p-type semiconductor.