Q.

Workdone during this cyclic process, starting from A is ......., q is .......
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a

–620.7, +620.7J

b

+620.73, +620.7J

c

+620.7J, –620.7J

d

zero, zero

answer is B.

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Detailed Solution

AB is isobaric process

BC is isochoric process

AC is isothermal process 

W = wAB+wBC+wAC

W=-PV+0+(2.303nRTlogVfinalVinitial)

W=-1(40-20)+0+2.303pvlog4020

W=-1(40-20)+0+2.303(1×20)log4020

W=-20+13.87 = - 6.13 lit -atm X 101.3 J/lit-atm = -620.9 J

since it is cyclic process E = 0

From first law of thermodynamics q = -w = 620.9 J

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