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Q.

Write the IUPAC name of : .K [ Co (CN) (CO)2(NO) ]  and calculate the oxidation number of cobalt in this complex.

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a

potassium dicarbonyl cyano nitrosyl cobaltate(0)

b

potassium cyano dicarbonyl nitrtro cobalt(1)

c

potassium cyano carbondioxygen notro cobaltate(0)

d

potassium carbonyl cyano carbonyl notroso(0)

answer is A.

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Detailed Solution

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 K [Co(CN ) (CO)2(NO)] is potassium dicarbonyI cyano nitrosyl Cobaltate (0). In this complex:

K+1 [Co (CN)-1(CO)0(NO)0]  Co  oxidation number=0

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