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Q.

Wrong statement about ionization enthalpies of d-block 

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a

For 3rd series transition metals I2>I3>I1

b

Order of third ionization enthalpies Cr2+<Mn2+>Fe2+<Co2+

c

Order of second ionization enthalpies V+<Cr+<Mn+<Fe+   

d

Increase in first ionization enthalpy is not regular

answer is D.

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Wrong statement about ionization enthalpies of d-block