Wrong statement among the following is

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If initial concentration increases half life decreases in zero order.

Effective collisions are more if activation energy is less.

Zero order reaction proceeds at a constant rate independent of concentration or time.

Reactions with highest rate constant values have lowest activation energies.

answer is D.

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Detailed Solution

The half-life of the zero order reaction is given as:

$T_{1 / 2} = \frac{{[A]}_{0}}{2 k}$

In this formula, the half life of the reaction is directly proportional to the concentration of the reactant. So, as the concentration of the reactant increases the half-life of the reaction also increases.

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