Q.

Wrongly matched structure and it's property is

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a

 Question Image(10) - annulene is not aromatic

b

Question Image   is antiaromatic but not non-aromatic

c

Question Image is non-aromatic but not anti aromatic

d

Question Image

rotation about the double bond connecting the rings is most feasible.

answer is A.

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Detailed Solution

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 Monocyclic, planar, conjugated, polyenes having [4nπ] electrons are antiaromatic.

 Cyclic, non planar-non aromatic.

Stability order : Aromatic > Non aromatic > Anti aromatic.

Question Image

First option is monocyclic, non planar,non aromatic

In second form both the rings acquires aromaticity and hence the above compound mainly exist in second form .In second form the two rings are connecting through single bond and hence free rotation about single bond is most feasible.

[10] annulene adopts non-planar geometry, due to repulsions among the trans annular hydrogens and hence, eventhough it follows the Huckel's rule it is non aromatic

 

 

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Wrongly matched structure and it's property is