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Q.

X and Y are trihalides of the IIIA group. Both hydrolysis liberates HCl gas. 'X' forms the tetrahedral product and 'Y' forms an octahedral product. X and Y are respectively

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a

AlCl3, GaCl3

b

BCl3 ; AlCl3

c

AlCl3, BCl3

d

BCl3 ; TiI3

answer is A.

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Detailed Solution

[B(OH)4]- ; [Al(H2O)6]+3

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X and Y are trihalides of the IIIA group. Both hydrolysis liberates HCl gas. 'X' forms the tetrahedral product and 'Y' forms an octahedral product. X and Y are respectively